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Nonreciprocal regulation of the redox state of the glutathioneglutaredoxin and thioredoxin systems

While GSH-AcH conjugates have not always been observed in vitro [50, 51], high concentrations of GSH in hepatocytes makes this reaction a likely candidate to explain GSH protection against EtOH toxicity

The body, more often than not, has less free cysteine available than the synthesis machinery would otherwise use

and G1, G2 etc.: designate peptide functional groups in glutathione and the corresponding G-site ligands of the glutathione 5-transferases, respectively G-site: glutathione-binding site H-site: hydrophobic electrophile-binding site